In addition to the colors on the wheel, you can make use of neutral colors -- black, white, and gray -- and earth tones such as brown, tan and olive to create certain effects. All make good backgrounds to accentuate other colors. Here, a dark background makes the foreground appear lighter. Lighter backgrounds will appear to darken blooms in the foreground.
You can use neutral colors as "punctuation" in the garden. Here, gray foliage plants and white flowers are useful to help separate combinations of plants using different color schemes.